Studies on organic fluorine compounds. XLIII. The ene reaction of hexafluoroacetone.

Determination of fluorine in organic compounds.

Thermochemistry of Organic Fluorine Compounds and Carbon Compounds

Rotating-bomb calorimetry was first applied to organic compounds that contain chlorine, bromine, or sulphur. Techniques developed for these classes of compounds, mostly at the University of Lund and at the Bureau of Mines in Bartlesville, have been described in the book Experimental Thermochemistry-, The development of rotating-bomb methods made accurate combustion calorimetry feasible for othe...

The aromatic ene reaction

The ene reaction is a pericyclic process in which an alkene with an allylic hydrogen atom (the ene donor) reacts with a second unsaturated species (the enophile) to form a new product with a transposed π-bond. The aromatic ene reaction, in which the alkene component is embedded in an aromatic ring, has only been reported in a few (four) instances and has proceeded in low yield (≤6%). Here, we s...

Studies of the Atmospheric Chemistry of Volatile Organic Compounds and of Their Atmospheric Reaction Products

An EPR Study of Heterogeneous Reaction of CH3O2 Radicals with Organic Compounds: Effect of Organic Compound and Surface Nature

The reaction of CH3O2 radicals with acetaldehyde on the solid surface of NH4NO3 has been studied in a flow capillary reactor at low pressure and room temperature. The experiments were performed using EPR spectrometer combined with the kinetic method of radicals freezing. Peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...